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1. W.W.Zorbach, J. Org. Chem. 23:1797 (1958)
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Steroid Glucuronides and Sulfates.
A table of their physico-chemical constants, structures and nomenclature.
COPYRIGHT © Harry E. Hadd, Ph.D., 1969
The compounds are listed in the table first by the Number of the Carbon Atom of
the Steroid bearing the Hydroxyl Group that is Conjuated and its Configuration,
viz., 3-Alpha Hydroxyl:
second by the Number of Carbon Atoms in the Steroid; third by the Glucuronide
and Sulfate of that Steroid.
The Structural Formula of each Steroid Conjugate is that of the
Free Acid.
Listed are the Physical Constants of the Steroid Glucuronides: Free Acid (G),
Sodium Salt (G-Na), acetylated methyl ester (GAc3); of the Steroid
Sulfates: Sodium Salt (Na+), Potassium Salt (K+), Ammonium Salt
(NH4+), Pyridinium Salt. The number in parenthesis is the Reference
Number to the listed conjugate. If the conjugate or derivative have been made,
the Melting Point and Optical Rotation are recorded. The Molecular Weight and
Elemental Composition are shown by % Composition of the individual atoms,
beneath which is the number of atoms in
the molecule.
** M is Na or K
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